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Diarylide Yellow HR

PY83

Alternate Name

Diarylide Yellow HR-70 (A different pigment formulation with the same pigment code- refer to notes)

Pigment Description

A pigment with two natures- and two lightfastness readings to match. Aside from the lightfastness confusion there are also health warnings so see those below. This warm orange-yellow is a very tricky pigment with two varieties which fly under the same pigment code. The problem is that the two distinct kinds of PY83 vary a lot in lightfastness.

In regard to PY83's lightfastness issues, we're grateful to Golden for illuminating the differences. One kind of PY83 has excellent lightfastness and is more opaque (the HR70 version), while the other form is transparent and has poor lightfastness. Unfortunately the current ASTM only ascribes one lightfastness code, which is applied by paintmakers in a blanket sort of way. So, the fading transparent version of PY83 is frequently mis-ascribed an excellent lightfastness rating, which truly only belongs to the other kind of PY83. The transparent, fugitive version has a lovely look to it, but terrible lightfastness. In the case of Golden, who made this discovery, they opted to keep the transparent version in their blends and adjust the low lightfastness rating to match. They shared a discussion of this as well as an illustration of how the transparent version compares to other pigments in the same color space.

In terms of health and safety, we were shocked to hear this is a problematic pigment due to benzidine (we advise all artists to research toxicity and benzidine in their pigments). This pigment metabolizes to a carcinogen-- Monona Rossol alerted us to this in her writing, more of her materials can be found here. It sounds like heating also creates a carcinogen. Additionally, contamination with PCBs is likely as well. There are also thresholds for limiting the dust so please consult proper handling.

Unfortunately, regarding the lightfastness confusion, it is hard to tell at a glance which of the two versions may be in any given tube of PY83. One hint may be to look at single pigment paints marked PY83 and assess whether the paintmaker lists them as transparent or very transparent. If so, they may be the fugitive kind, regardless of the lightfastness reading given by the manufacturer.

Resources

PY83 pigment data from David G. Myers, The Color of Art Pigment Database, Artiscreation.com

Information about PY83 from Bruce MacEvoy, Handprint Guide to Watercolors, General information about this class of pigments from Handprint,

Sands, Sarah (2015, October 1). Beauty and the Best, Wrestling with Changes at Williamsburg https://justpaint.org/beauty-and-the-best-wrestling-with-changes-in-williamsburg/. Just Paint, Golden Artist Colors,

Rossol, Monona. The Artist's Complete Health and Safety Guide. New York, NY : Allworth Press, 2001. The book is rather dated, updated information is available from her website.

Stats

Lightfastness

Varies- two kinds of the pigment with very different lightfastness

The opaque version (HR-70) is given LFI- Excellent by the ASTM. The transparent version, which is not differentiated on the ASTM table, was found to be the equivalent of LF III- Poor in tests done by Golden. It would be advisable to do one's own lightfastness testing.

Transparency

Varies

Two versions, one opaque (HR-70) and the other transparent

Toxicity

Previously thought to be in the category of Low Concern, new research suggests this pigment is problematic

This pigment metabolizes to a carcinogen and also does this when heated-- Monona Rossol alerted us to this in her writing, more of her materials can be found here. It sounds like contamination with PCBs may be likely. There are also thresholds for limiting the dust (as it is also related to causing cancer) so please consult experts for proper handling. This pigment is related to benzidine. We are not toxicology experts, so please consult SDS as well as third party experts for best practices.

Chemical Name

Disazo

Dry Pigments listing PY83

DISCLAIMER: Please note that we are not experts in health and safety and we are not toxicologists, please consult the proper experts. We are not liable for any issues that may arise from the use of our website or its contents. The information contained in this site is provided without warranty or guarantee of any kind. We do not necessarily endorse any other website that are linked from our site. For any important pigment specs, please reference the manufacturer details. If you discover errors or omissions, please reach out through our contact form. Thank you.

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