Benzimidazolone Yellow H3G
A yellow that has gained some notoriety. Benzimidazolone Yellow is usually found as a bright middle yellow, PY154, but it may also be a deep caramel or orangey brown. It is one of several benzimidazolone yellows, and in general comes highly recommended for lightfastness.

PY154 is a famous benzimidazolone yellow that is sometimes described as an alternative to Aureolin, PY40, also known as cobalt yellow, but having worked with Aureolin, the comparison has a little merit... but not quite enough to say they are similar. The browner form of PY154 could be a bit like Aureolin, which is browner in masstone but more yellow when spread thinly- however Aurolin has a different character. The yellower/brighter form of PY154 may also be recommended as a replacement for other more modern yellows, such as PY73, a Hansa Yellow. Benzimidazolone Yellow, as PY154 tends to have far better lightfastness.

Another PY154 with different coloring. RGH Benzimidazolone Yellow
While perhaps not perfect, the lightfastness of PY154 is rated very highly, and artiscreation lists several sources that show all 8's (highest marks) on the Blue Wool Scale for lightfastness testing. Golden chose PY154 to replace one of their other yellow pigments, as described in this article. In Schmincke's watercolors they assign it four out of five stars for lightfastness, with five tending to describe the bulletproof lightfastness of some of the earth tones, so a four means very high in lightfastness.

PY154, Azo Yellow, in Daniel Smith Oils, which have been discontinued
In terms of health, Monona Rossol's work notes that the chemical in PY154 may metabolize to create something that causes or is related to causing methemoglobinemia.

The browner form of PY154, which is more yellow when spread thinly. RGH Benzimidazolone Yellow
PY154 pigment data from David G. Myers, The Color of Art Pigment Database, Artiscreation.com
Information about PY154 from Bruce MacEvoy, Handprint Guide to Watercolors, General information about this class of pigments from Handprint,
Spurgeon, Tad. Living Craft: A Painter's Process. Mt. Airy, Philadelphia, PA: Zoetrope, 2018. Newer version available here: https://www.thomaskitts.com/page/36804/tad-spurgeons-living-craft,
Rossol, Monona. The Artist's Complete Health and Safety Guide. New York, NY : Allworth Press, 2001. The book is rather dated, updated information is available from her website.
Excellent
Considered to be ASTM I. This particular pigment was not mentioned in Golden’s recent testing with mixing whites in oil. The NPIRI from the 1980s only listed indoor tests but they were solid.
Semi-Opaque, Semi-Transparent
Previously thought to be Lower Concern, however new research indicates there may be hazards
Data is low, but may metabolize to create something that causes or is related to causing methemoglobinemia. See Monona Rossol's research available upon request here for more information. Treat all pigments and paints with studio safety protocols.
monoazo, acetoacetyl, H3G, benzimidazolone
C₁₈H₁₄F₃N₅O₃
DISCLAIMER: Please note that we are not experts in health and safety and we are not toxicologists, please consult the proper experts. We are not liable for any issues that may arise from the use of our website or its contents. The information contained in this site is provided without warranty or guarantee of any kind. We do not necessarily endorse any other website that are linked from our site. For any important pigment specs, please reference the manufacturer details. If you discover errors or omissions, please reach out through our contact form. Thank you.
