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Top Pigment

Natural Brown Iron Oxide

PBr7

Alternate Names

Burnt Sienna

Burnt Umber

Raw Sienna

Raw Umber

Metallic Brown

Pigment Description

Deep brown, light brown, black brown, chocolate brown, red brown, chestnut, sable, and near black--which one would you like? PBr7 covers a wide range of brownish colors and is one of the largest single-pigment paint categories in artists' oils. Brown Earth or more technically Brown Iron Oxide is available in many different color variants.

A swatch of brown oil paint made from Brown Iron Oxide

Williamsburg Burnt Umber, made with PBr7

Classic names such as Burnt Sienna, Raw Sienna, Burnt Umber, and Raw Umber are at home under this pigment code. Certain countries and locations became famous for their natural brown earth colors and place names such as Sienna and Umber became associated with the colors they produced locally. Over time these names took on a life of their own and the place names no longer dictate the origin of the pigment. However there are certain expectations for the general color associated with them.

A stroke of oil paint made with a warm brown earth, or brown iron oxide PBr7

Vasari Burnt Sienna,

In addition to the most famous names for PBr7 (Umbers and Siennas) there are a handful of other PBr7 names which have become part of the unofficial cannon. Expect to find Violet Hematites, Burnt Yellow Ochres (which turn reddish), Cassel Earths, Van Dyke Browns, Turkey Umbers, and more.

Pigment image

We must briefly caution that burnt umber as well as other umbers may cause problems in oil painting. That goes beyond the scope of this entry so consult conservation experts for more.

Pigment image

Vasari Raw Sienna, is also made of PBr7. The color range for PBr7 is rather vast

Pigment image

Paints made with PBr7 can range from yellow, orange, red, brown, violet, or even greenish.

In terms of working properties the texture and the opacity can vary almost as much as the hues.

Pigment image

A pigment with many moods and expressions- the code PBr7 covers a wide array of colors. PBr7 is abundantly available as an earth tone, and due to its many versions it is the most common single-pigment paint in oils. Each version will usually have a different name. All these swatches of oil paint are single-pigment PBr7 paints

The Artist's Guide to Health and Safety has more information about health issues associated with Iron and Manganese, and if there are other impurities the relevant sections need to be consulted. Her updated work can be found through her site.

Burnt Sienna oil paint made from Natural Brown Oxide

Williamsburg Italian Burnt Sienna, made with PBr7

A swoosh of brown oxide oil paint

Williamsburg Raw Umber, made with PBr7

Finally, there is a disturbing trend wherein paint companies are making convenience blends of multiple colors to emulate earth tones instead of using earth tones. Bear in mind that depending on the pigments used, the blends used to emulate the earths will often not have the same stability.

Resources

PBr7 pigment data from David G. Myers, The Color of Art Pigment Database, Artiscreation.com,

Elliott, Virgil. Traditional Oil Painting. Echo Point Books & Media, LLC, 2019. https://amzn.to/4nwIdzq,

Spurgeon, Tad. Living Craft: A Painter's Process. Mt. Airy, Philadelphia, PA: Zoetrope, 2018. Newer version available here: https://www.thomaskitts.com/page/36804/tad-spurgeons-living-craft,

Information about PBr7 from Bruce MacEvoy, Handprint Guide to Watercolors, General information about this class of pigments from Handprint

Stats

Lightfastness

Excellent

Generally this pigment is thought to be among the most lightfast. However Golden’s Lightfastness Testing in oils revealed a slight sensitivity in a particular Raw Umber to Flake White in linseed oil, though this may be brand dependent. In general PBr7 performed at the expected ASTM I. There are many forms and colors of PBr7 and we would expect them to perform at ASTM I as well.

Transparency

Varies, Transparent, Opaque

Varies, Transparent. Raw Umber and Raw Sienna, tend to be Semi-transparent. Some PBr7s are Opaque. The NPIRI notes that “Metallic Browns are opaque; Burnt Siennas are transparent in oil.” This is just a guideline, individual modern paints vary

Toxicity

Previously thought to be in the category of lesser concern, however may contain impurities

May contain manganese and other impurities. The Artist's Guide to Health and Safety has more information about health issues associated with Iron and Manganese, and if there are other impurities the relevant sections need to be consulted. Her updated work can be found through her site. It is possible that the hazard of free silica could be present so to rule this out please check with the supplier. Treat all pigments and paints with studio safety protocols.

Dry Time

Varies

Varies. Umbers dry very quickly naturally (1-2 days). For other PBr7s, 2-7 days is fairly typical.

Oil Content

Varies, Low to Very High

Varies considerably depending on the pigment. By volume, Raw Umber particularly is a paint that requires a lot of oil. A chart by Williamsburg shows a comparison. Mayer also categorizes it as high oil volume with a score of 103, and there is general agreement. Mars Violet often has a fairly low requirement by volume, some say the lower end of medium depending on the particular pigment. Burnt Sienna can vary from medium to very high as well. Mayer assigns Raw Sienna a high oil volume with a score of 118, with Burnt Sienna at 129 and Burnt Umber at 136.

Chemical Name

Ferrosoferric oxide, calcined natural iron oxide containing manganese

with PBr7 (Natural Brown Iron Oxide)
No single-pigment Oil found with PBr7

DISCLAIMER: Please note that we are not experts in health and safety and we are not toxicologists, please consult the proper experts. We are not liable for any issues that may arise from the use of our website or its contents. The information contained in this site is provided without warranty or guarantee of any kind. We do not necessarily endorse any other website that are linked from our site. For any important pigment specs, please reference the manufacturer details. If you discover errors or omissions, please reach out through our contact form. Thank you.

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