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    Top Pigment

    Natural Brown Iron Oxide

    PBr7

    Alternate Names

    Burnt Sienna

    Burnt Umber

    Raw Sienna

    Raw Umber

    Metallic Brown

    Pigment Description

    Deep brown, light brown, black brown, chocolate brown, red brown, chestnut, sable, and near black--which one would you like? PBr7 covers a wide range of brownish colors and is one of the largest single-pigment paint categories in artists' oils. Brown Earth or more technically Brown Iron Oxide is available in many different color variants.

    A swatch of brown oil paint made from Brown Iron Oxide

    Williamsburg Burnt Umber, made with PBr7

    Classic names such as Burnt Sienna, Raw Sienna, Burnt Umber, and Raw Umber are at home under this pigment code. Certain countries and locations became famous for their natural brown earth colors and place names such as Sienna and Umber became associated with the colors they produced locally. Over time these names took on a life of their own and the place names no longer dictate the origin of the pigment. However there are certain expectations for the general color associated with them.

    A stroke of oil paint made with a warm brown earth, or brown iron oxide PBr7

    Vasari Burnt Sienna,

    In addition to the most famous names for PBr7 (Umbers and Siennas) there are a handful of other PBr7 names which have become part of the unofficial cannon. Expect to find Violet Hematites, Burnt Yellow Ochres (which turn reddish), Cassel Earths, Van Dyke Browns, Turkey Umbers, and more.

    Pigment image

    We must briefly caution that burnt umber as well as other umbers may cause problems in oil painting. That goes beyond the scope of this entry so consult conservation experts for more.

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    Vasari Raw Sienna, is also made of PBr7. The color range for PBr7 is rather vast

    Pigment image

    Paints made with PBr7 can range from yellow, orange, red, brown, violet, or even greenish.

    In terms of working properties the texture and the opacity can vary almost as much as the hues.

    Pigment image

    A pigment with many moods and expressions- the code PBr7 covers a wide array of colors. PBr7 is abundantly available as an earth tone, and due to its many versions it is the most common single-pigment paint in oils. Each version will usually have a different name. All these swatches of oil paint are single-pigment PBr7 paints

    The Artist's Guide to Health and Safety has more information about health issues associated with Iron and Manganese, and if there are other impurities the relevant sections need to be consulted. Her updated work can be found through her site.

    Burnt Sienna oil paint made from Natural Brown Oxide

    Williamsburg Italian Burnt Sienna, made with PBr7

    A swoosh of brown oxide oil paint

    Williamsburg Raw Umber, made with PBr7

    Finally, there is a disturbing trend wherein paint companies are making convenience blends of multiple colors to emulate earth tones instead of using earth tones. Bear in mind that depending on the pigments used, the blends used to emulate the earths will often not have the same stability.

    Resources

    PBr7 pigment data from David G. Myers, The Color of Art Pigment Database, Artiscreation.com,

    Elliott, Virgil. Traditional Oil Painting. Echo Point Books & Media, LLC, 2019. https://amzn.to/4nwIdzq,

    Spurgeon, Tad. Living Craft: A Painter's Process. Mt. Airy, Philadelphia, PA: Zoetrope, 2018. Newer version available here: https://www.thomaskitts.com/page/36804/tad-spurgeons-living-craft,

    Information about PBr7 from Bruce MacEvoy, Handprint Guide to Watercolors, General information about this class of pigments from Handprint

    Stats

    Lightfastness

    Excellent

    Generally this pigment is thought to be among the most lightfast. However Golden’s Lightfastness Testing in oils revealed a slight sensitivity in a particular Raw Umber to Flake White in linseed oil, though this may be brand dependent. In general PBr7 performed at the expected ASTM I. There are many forms and colors of PBr7 and we would expect them to perform at ASTM I as well.

    Transparency

    Varies, Transparent, Opaque

    Varies, Transparent. Raw Umber and Raw Sienna, tend to be Semi-transparent. Some PBr7s are Opaque. The NPIRI notes that “Metallic Browns are opaque; Burnt Siennas are transparent in oil.” This is just a guideline, individual modern paints vary

    Toxicity

    Previously thought to be in the category of lesser concern, however may contain impurities

    May contain manganese and other impurities. The Artist's Guide to Health and Safety has more information about health issues associated with Iron and Manganese, and if there are other impurities the relevant sections need to be consulted. Her updated work can be found through her site. It is possible that the hazard of free silica could be present so to rule this out please check with the supplier. Treat all pigments and paints with studio safety protocols.

    Dry Time

    Varies

    Varies. Umbers dry very quickly naturally (1-2 days). For other PBr7s, 2-7 days is fairly typical.

    Oil Content

    Varies, Low to Very High

    Varies considerably depending on the pigment. By volume, Raw Umber particularly is a paint that requires a lot of oil. A chart by Williamsburg shows a comparison. Mayer also categorizes it as high oil volume with a score of 103, and there is general agreement. Mars Violet often has a fairly low requirement by volume, some say the lower end of medium depending on the particular pigment. Burnt Sienna can vary from medium to very high as well. Mayer assigns Raw Sienna a high oil volume with a score of 118, with Burnt Sienna at 129 and Burnt Umber at 136.

    Chemical Name

    Ferrosoferric oxide, calcined natural iron oxide containing manganese

    with PBr7 (Natural Brown Iron Oxide)
    No single-pigment Oil found with PBr7

    DISCLAIMER: Please note that we are not experts in health and safety and we are not toxicologists, please consult the proper experts. We are not liable for any issues that may arise from the use of our website or its contents. The information contained in this site is provided without warranty or guarantee of any kind. We do not necessarily endorse any other website that are linked from our site. For any important pigment specs, please reference the manufacturer details. If you discover errors or omissions, please reach out through our contact form. Thank you.

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