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Top Pigment

Mars Black, Iron Oxide Black

PBk11

Alternate Names

Mineral Black

Black Iron Oxide

Synthetic Black Oxide

Magnetic Iron Oxide

Pigment Description

Mars Black is an important artist color which is actually, strangely, magnetic. It is reported to have excellent lightfastness. Technically Ferroso-ferric oxide, this can be thought of like a black earth or Black Iron Oxide.

An impasto stroke of Mars Black oil paint

Old Holland Mars Black in oil paint, pigment PBk9

As a side note, Mars Black sometimes contains manganese black, so keep that in mind as far as the health risks associated with manganese - see the Artist's Guide to Health and Safety for information about the hazards associated, as she notes it is sometimes mixed with PBk14, Manganese Black. Her updated work can be found through her site.

A painterly dollop of Mars Black in Oil Paint

Vasari Mars Black Oil paint. Typical to Vasari's trademark style, this is a smooth version of PBk9 pigment in oil

Among black pigments, Mars Black is one of the better driers in oils. Mars Black is a solid, durable pigment choice which comes in various grades depending on the particle size. Normally the consistency is very smooth, but natural versions tend to be grittier. Vasari's French Ivory Black has a different texture as it is made of "Natural Black Iron Oxide and plant based charcoal." So even though they call it Ivory Black it actually contains PBk11.

Pigment image

Vasari French Ivory Black. Normally Ivory Black is PBk9, but this version is PBk11. They offer several versions of PBk11 made into paint

Samples of Mars Black such as Williamsburg's German Earth have a visible texture. There seem to be a few naturally occurring pigment sources, which have the nice effect of softening the intensity of Mars Black just a little - otherwise this is a powerful pigment.

Pigment image

Williamsburg German Black, PBk11

As a pigment for painting, PBk11 has quite a few advantages. Mars Black doesn't take as much oil to make a paint as some of the other major black pigments (for example Lamp Black) and it also has better drying properties.

A textured application of Mars Black

Blockx Mars Black

Resources

PBk11 pigment data from David G. Myers, The Color of Art Pigment Database, Artiscreation.com, Spurgeon, Tad. Living Craft: A Painter's Process. Mt. Airy, Philadelphia, PA: Zoetrope, 2018. Newer version available here: https://www.thomaskitts.com/page/36804/tad-spurgeons-living-craft,

Information about PBk11 from Bruce MacEvoy, Handprint Guide to Watercolors,

Stats

Lightfastness

Excellent

Generally considered to be among the most lightfast pigments, ASTM I.

Transparency

Varies, Opaque

Some formulations are extremely opaque. It is possible for it to be semi-opaque or even semi-transparent.

Toxicity

Previously thought to be Lower Concern, may be hazardous

NPIRI mentions that natural PBk11 may contain the hazard of free silica. Treat all pigments and paints with studio safety protocols.

Tinting

Good

Dry Time

Fast to Medium

Some list Fast (1-2 days), others Medium, 2-7 days. Naturally dries faster than other black pigments. Shorter drying times may contain driers

Oil Content

Sources Vary

Sources disagree somewhat, some medium by volume, others high. By weight, Artiscreation lists 15 g/100g of oil.

Chemical Name

Synthetic black iron oxide, or magnetic Black Iron Oxide, Ferro-ferric oxide

with PBk11 (Mars Black, Iron Oxide Black)
No single-pigment Oil found with PBk11

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